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Raina V. Gough, Jason A. Widegren, Thomas J. Bruno
The global thermal decomposition kinetics of JP-7, JP-TS and JP-900 were studied. Decomposition reactions were performed at 375, 400, 425, and 450 °C in stainless-steel ampule reactors. At each temperature, the extent of decomposition as a function of time
Petroleum is a complex fluid whose sulfur content varies considerably depending on its place of origin. Sour crude petroleum, which contains more than 0.5 % sulfur by mass, often requires additional processing due to the potential for corrosion and
Steven J. Christopher, Stephen E. Long, Renata Amais, Joaquim N?ga
A method is described for quantification of sulfur at low concentrations on the order of 10 µg g-1 in biodiesel and diesel fuels using double isotope dilution and sector field inductively coupled plasma mass spectrometry (ID-SF-ICP-MS). Closed vessel
E.K. Michailidou, Marc J. Assael, Marcia L. Huber, Richard A. Perkins
This paper contains new, representative reference equations for the viscosity of n-hexane. The equations are based in part upon a body of experimental data that has been critically assessed for internal consistency and for agreement with theory whenever
Expanding on earlier viscosity measurements of rocket propellants from 293 K to 373 K at atmospheric pressure, the viscosity of rocket propellant RP-2 was measured from 270 K to 450 K with pressures to 137 MPa. The instrument was an oscillating piston
Alexander Y. Smolyanitsky, Andrei F. Kazakov, Thomas J. Bruno, Marcia L. Huber
A well-established interaction potential, the Optimized Potential for Liquid Simulation All-Atom (OPLS-AA) force-field, within the MD framework was used to determine self- and mutual diffusivity of several near-critical and supercritical fluids. The test
This is a new release of the NIST Standard Reference Database 23, commonly known as REFPROP. Enhancements have been made to most areas of the NIST REFPROP program, including the graphical interface, the Excel spreadsheet, the FORTRAN files (i.e., core
Density, speed of sound, and viscosity have been measured for samples of RP-1 and RP-2 that were stressed for 0.5 min at 475 °C and 510 °C at a pressure of 17 MPa. Density and speed of sound were measured from 5 °C to 50 °C for the samples stressed at 475
Ocean-going ships burn heavy fuel oil. The combustion of heavy fuel oil in marine diesel engines emits nitrogen oxides, sulfur oxides, and particulates into the air. Growing public concern over air quality has led to increased scrutiny of heavy fuel oil as
One of the most important properties measured for liquid fuels is the volatility, usually as expressed by the distillation curve. In previous work, we introduced the composition explicit or advanced distillation curve (ADC) metrology, which we have applied
Andrea Comandini, Iftikhar A. Awan, Jeffrey A. Manion
Complementary shock-tube studies at the National Institute of Standards and Technology (NIST) and the University of Illinois at Chicago (UIC) have been used to examine the decomposition reactions of the 1-pentyl radical at temperatures of 833 K to 1130 K
Additive packages are used with aviation kerosenes to achieve performance enhancements such as higher or lower operating temperatures or increased lubricity. An additive used to increase operating temperatures for heat sink applications is the +100
Thomas J. Bruno, Tara J. Fortin, Tara M. Lovestead, Jason A. Widegren
The complex nature of finished fuels makes definitive studies on composition and combustion properties very difficult and uncertain. This has led to the adoption of fuel surrogate mixtures in such studies. The development of a surrogate mixture is itself a