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Diego Ortiz Vega, Kenneth Hall, James Holste, Allan H. Harvey, Eric W. Lemmon
This report documents the equation of state for fluid helium implemented in Version 10 of NIST's REFPROP Standard Reference Database. The equation of state is expressed as the molar Helmholtz energy as a function of temperature and density, and is valid
Ian Bell, Jacob Leachman, Albert Rigosi, Heather Hill
The extreme conditions have limited the availability and accuracy of experimental thermophys- ical property measurements for cryogens, particularly transport properties. Traditional scaling techniques such as corresponding states theory have long been
Jeffrey Ethier, Debra Audus, Devin Ryan, Richard Vaia
Flory-Huggins (FH) theory is foundational to understanding macro-phase separation in polymer solutions; however, its predictions often quantitatively disagree with experiment. Recent machine-learning (ML) methods have generated predictive models of phase
Xin Yuan, Harold Hatch, Jacinta Conrad, Amanda Marciel, Jeremy Palmer
We use molecular simulation to investigate the pH response of sequence-controlled polyampholyte brushes (PABs) with polymer chains consisting of alternating blocks of weakly acidic and basic monomers. Changes in the ionization state, height, lateral
Ryan Snodgrass, Gregory Swift, Joel Ullom, Scott Backhaus
Under some circumstances, pulse tube refrigerator regenerators operating in the real-fluid regime can absorb a large amount of heat between their warm and cold ends without a decrease to cooling power at their cold heat exchanger. Experiments and analysis
Harold Hatch, Daniel Siderius, Jeffrey Errington, Vincent K. Shen
Recent interest in parallelizing flat-histogram transition-matrix Monte Carlo simulations in the grand canonical ensemble, due to its demonstrated effectiveness in studying phase behavior, self-assembly and adsorption, has led to the most extreme case of
This article reviews the state of knowledge of the thermophysical properties of water in all its phases and the reference formulations that provide standardized, recommended values for these properties for use in science and industry. The main focus of the
Kehui Gao, Jiangtao Wu, Ian Bell, Allan H. Harvey, Eric W. Lemmon
Fluid ammonia is highly associated because of strong intermolecular hydrogen bonding. This causes different behavior of thermophysical properties from nonpolar fluids, as reflected for example in the heat capacity. In this work, a new equation of state
Ala Bazyleva, William E. Acree, Vladimir Diky, Glenn T. Hefter, Johan Jacquemin, M. Clara F. Magalhaes, Joe W. Magee, Kirk Nordstrom, John O'Connell, James D. Olson, Ilya Polishuk, Kurt A. G. Schmidt, John M. Shaw, J. P. Martin Trusler, Ronald D. Weir
This article is the second of three projected IUPAC Technical Reports on reference materials for phase equilibrium studies. The goal of this project was to select reference systems with critically evaluated property values for the verification of
Entropy scaling relates dynamic and thermodynamic properties by reducing the viscosity to be a function of only the residual entropy. Molecular simulations are used to investigate the entropy scaling of the viscosity of three models of sodium chloride and
Closed-cycle dilution refrigerators (DRs) recirculate 3He from the still via condensation on a cooled surface; condensate from the cooled surface drips down toward the mixing chamber via gravity. Compact versions of these DRs are being considered for
Resistance thermometry, meticulously developed over the last century, provides a time-tested method for taking temperature measurements. However, fundamental limits to resistance-based approaches along with a desire to reduce the cost of sensor ownership
The total power flow through cryocooler regenerators is key to their performance because it reduces the cooling available at the cold heat exchanger. At temperatures near 4 K, the real-fluid properties of helium and the finite-heat-capacity of regenerator