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Search Publications by: Jeffrey A. Manion (Fed)

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Displaying 51 - 75 of 112

Annual Report to Sponsor: Understanding Unwanted Combustion Enhancement by Potential Halon Replacements

February 3, 2012
Author(s)
Gregory T. Linteris, Jeffrey A. Manion, Donald R. Burgess Jr., Iftikhar A. Awan, Peter B. Sunderland, John L. Pagliaro
This year, we continued work to numerically model the behavior of the Halon replacements in the FAA Aerosol Can Test (FAA-ACT) to understand why they are causing more overpressure rather than flame extinction. The goal is to understand the process to

Standard Reactions for Comparative Rate Studies: Experiments on the Dehydrochlorination Reactions of 2 Chloropropane, Chlorocyclopentane and Chlorocyclohexane

November 23, 2011
Author(s)
Iftikhar A. Awan, Donald R. Burgess Jr., Wing Tsang, Jeffrey A. Manion
Single pulse shock tube studies of the thermal dehydrochlorination reactions (chlorocyclopentane → cyclopentene + HCl) and (chlorocyclohexane → cyclohexene + HCl) at temperatures of 843 to 1021 K and pressures of 1.4 to 2.4 bar have been carried out using

Reversed-Flow Chromatographic Determination of Binary Diffusion Coefficients

September 19, 2011
Author(s)
William S. McGivern, Jeffrey A. Manion
A reversed-flow chromatographic apparatus for the measurement of binary diffusion coefficients is described. Hydrocarbons are detected using flame ionization detection, and inert species can be detected by thermal conductivity. We have measured the binary

H Atom Attack on Propene

March 15, 2011
Author(s)
Claudette M. Rosado-Reyes, Jeffrey A. Manion, Wing Tsang
The reaction of propene(CH3CH=CH2) with hydrogen atoms has been investigated in a heated single-pulsed shock tube at temperature between 929K-1212K and pressures of 1.7bar-3.4bar. Stable products from H atom addition and H abstraction have been identified

The Decomposition and Isomerization of 5-Methylhex-1-yl Radical

July 9, 2010
Author(s)
Iftikhar A. Awan, William S. McGivern, Wing Tsang, Jeffrey A. Manion
The decomposition and isomerization reactions of the 5-methylhex-1-yl radical (1-5MeH) have been studied at temperatures of 889 K to 1064 K and pressures of 1.6 bar to 2.2 bar using the single pulse shock tube technique. The radical of interest was

Kinetics of the Thermal Reaction of H Atoms with Propyne

April 15, 2010
Author(s)
Claudette M. Rosado-Reyes, Jeffrey A. Manion, Wing Tsang
The reaction of hydrogen atoms with propyne(CH≡CCH3) has been investigated in a heated single pulse shock tube at temperatures of 870-1145K and pressures of 2-9 bar. Stable products from various reaction channels (terminal and non-terminal H addition, and

Soot Precursors from Real Fuels: The Unimolecular Reactions of Fuel Radicals

October 16, 2008
Author(s)
Wing Tsang, Iftikhar A. Awan, William Sean McGivern, Jeffrey A. Manion
This paper describes studies aimed at defining in a quantitative fashion the cracking pattern of fuel radicals under combustion conditions. The experimental procedure involves studies using a single pulse shock tube and combining the observations with