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Joseph P. Rice, Jerald Harder, Martin Snow, Thomas Woods
Over 30 scientists and calibration specialists gathered at the National Institute of Standards and Technology (NIST) in Gaithersburg, Maryland, for the first Solar Spectral Irradiance (SSI) Variations Workshop, Feb. 28-March 1, 2012. The purpose of the
Highly accurate spectroscopic models for O2 A-band absorption are required in numerous satellite- and ground-based remote sensing measurements of atmospheric greenhouse gases. In this study, we quantify the sensitivity of the calculated A-band transmission
Vladimir L. Orkin, Victor Khamaganov, Michael J. Kurylo III
Rate constants for the gas phase reactions of OH radicals with 2-propanol and three fluorine substituted 2-Propanols, (CH3)2CHOH (k0), CF3)2COH (k1), (CF3)2C(OH)CH3 (k2), and (CF3)3COH (k3) were measured using a flash photolysis resonance-fluorescence
Alexander M. Zolot, Fabrizio R. Giorgetta, Esther Baumann, Jeffrey W. Nicholson, William C. Swann, Ian R. Coddington, Nathan R. Newbury
We demonstrate a dual comb spectrometer using stabilized frequency combs spanning 176 THz to 219 THz (1370 nm to 1700 nm) in the near infrared. Measurements of amplitude and phase response at each individual comb tooth span the full 43 THz, generating ~430
Alexander M. Zolot, Fabrizio R. Giorgetta, Esther Baumann, William C. Swann, Jeff Nicholson, Ian R. Coddington, Nathan R. Newbury
Most spectroscopic instruments directly measure optical wavelength, which is converted to frequency and calibrated against spectral features that have traditionally been measured using complicated frequency chain methods. In the past decade optical
Kenneth O. Patten, Victor Khamaganov, Vladimir L. Orkin, Steven L. Baughcum, Donald J. Wuebbles
The rate constant for the gas phase reaction of OH radicals with BTP (2-Bromo-3,3,3-trifluoropropene, CH2=CBrCF3) was measured using a flash photolysis resonance-fluorescence technique over the temperature range 220 K to 370 K. The Arrhenius plot was found
This study provides an analysis of the uncertainty of carbon dioxide (CO2) emissions from an 8 MW natural gas burner. A precise and accurate point source for industrial quantities of carbon dioxide can be used to evaluate the performance of stack gas
Joseph T. Hodges, David A. Long, Mitchio Okumura, Charles E. Miller
Carbon dioxide (CO2) isotopic ratios were measured at 1.6 μm through the use of frequency-stabilized cavity ring-down spectroscopy (FS-CRDS). We report the highest spectrum signal-to-noise ratios to date for CO2 transitions, with values as high as 28,000:1
Pedro Bueno, Daniel K. Havey, George W. Mulholland, Joseph T. Hodges, Keith A. Gillis, Russell R. Dickerson, Michael R. Zachariah
A quantitative understanding of the absorption and scattering properties of mixed soot and aerosol particles is necessary for evaluating the Earth's energy balance. Uncertainty in the net radiative forcing of atmospheric aerosols is relatively large and
Alexander M. Zolot, Ian R. Coddington, Fabrizio R. Giorgetta, Esther Baumann, William C. Swann, Nathan R. Newbury
A coherent dual comb spectrometer spanning much of the near infrared was constructed from broadened erbium fiber lasers. Gas phase water, methane and acetylene spectra were measured and characterized toward establishing new frequency standards.
Stephen A. Montzka, S. Reimannander, Andreas Engel, Kirstin Kruger, O?Doherty Simon, William T. Sturges , Donald R. Blake , Marcel Dorf Dorf, Paul J. Fraser , Lucien Froidevaux , Kenneth Jucks, Karin Kreher, Michael J. Kurylo III, Abdelwahid Mellouki , John Miller , Ole J. Nielsen , Vladimir L. Orkin, Ronald G. Prinn , Robert Rhew , Michelle L. Santee , Andreas Stohl , Daniel P. Verdonik
The present document will be part of the information upon which the Parties to the United Nations Montreal Protocol will base their future decisions regarding protection of the stratospheric ozone layer. OVERVIEW It has been recognized since the 1970s that
Mingdong M. Li, Suvajyoti S. Guha, Rebecca A. Zangmeister, Michael J. Tarlov, Michael R. Zachariah
Electrospray (ES) sources are commonly used to introduce non-volatile materials (e.g. nanoparticles, proteins, etc.) in to the gas phase for characterization by mass spectrometry and ion mobility. Recent studies in our group using electrospray ion mobility
Vladimir L. Orkin, Victor Khamaganov, Larissa E. Martynova, Michael J. Kurylo III
Rate constants for the gas phase reactions of OH radicals with ethanol and three fluorinated ethyl alcohols, CH3CH2OH (k0), CH2FCH2OH (k1), CHF2CH2OH (k2), and CF3CH2OH (k3) were measured using a flash photolysis resonance-fluorescence technique over the