U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

Environment

Greenhouse Gas Measurements

Search Publications

Search Title, Abstract, Conference, Citation, Keyword or Author
  • Published Date
Displaying 301 - 325 of 367

High Accuracy Measurements of OH Reaction Rate Constants and IR and UV Absorption Spectra: Ethanol and Partially Fluorinated Ethyl Alcohols.

March 4, 2011
Author(s)
Vladimir L. Orkin, Victor Khamaganov, Larissa E. Martynova, Michael J. Kurylo III
Rate constants for the gas phase reactions of OH radicals with ethanol and three fluorinated ethyl alcohols, CH3CH2OH (k0), CH2FCH2OH (k1), CHF2CH2OH (k2), and CF3CH2OH (k3) were measured using a flash photolysis resonance-fluorescence technique over the

Rate Constants for the Reactions between OH and Perfluorinated Alkenes

February 20, 2011
Author(s)
Vladimir L. Orkin, Gregory A. Poskrebyshev, Michael J. Kurylo III
The rate constants for the reactions of OH radicals with fully fluorinated alkenes containing different number of –CF3 groups next to olefinic carbon, CF2=CF2, CF2=CFCF3, CF3CF=CFCF3, (CF3)2C=CFC2F5 were measured using the flash photolysis resonance

Performance of a coherent dual frequency comb spectrometer

January 1, 2011
Author(s)
Nathan R. Newbury, Esther Baumann, Ian R. Coddington, Fabrizio R. Giorgetta, William C. Swann, Alexander M. Zolot
We discuss the performance of a coherent dual frequency comb spectrometer in terms of signal-to-noise ratio, resolution, and accuracy based on experimental data in the near and short-wave infrared centered at 1.5 and 3.4 micrometers.

Broadband coherent spectroscopy in the near infrared using dual coherent frequency combs

August 15, 2010
Author(s)
Nathan R. Newbury, Ian R. Coddington, Esther Baumann, Fabrizio R. Giorgetta, William C. Swann, Alexander M. Zolot
Fiber-based frequency combs can provide broadband coherent light that enables new possibilities for high-accuracy, high-resolution broadband spectroscopy. We use a configuration with two coherently phase-locked combs; the output of one comb passes through

Standard Photoacoustic Spectrometer: Model and Validation using O2 A-Band Spectra

June 30, 2010
Author(s)
Keith A. Gillis, Daniel K. Havey, Joseph T. Hodges
We model and measure the absolute response of an intensity-modulated photoacoustic spectrometer comprising a 10 cm long resonator and having a Q-factor of approximately 30. We present a detailed theoretical analysis of the system and predict its response

Kinetics of the Thermal Reaction of H Atoms with Propyne

April 15, 2010
Author(s)
Claudette M. Rosado-Reyes, Jeffrey A. Manion, Wing Tsang
The reaction of hydrogen atoms with propyne(CH≡CCH3) has been investigated in a heated single pulse shock tube at temperatures of 870-1145K and pressures of 2-9 bar. Stable products from various reaction channels (terminal and non-terminal H addition, and

A proposed global atmospheric monitoring networkbased on standard stars

November 2, 2009
Author(s)
Gerald T. Fraser, Steven W. Brown, Keith R. Lykke, John T. McGraw, Allan W. Smith, John T. Woodward IV, Peter C. Zimmer, Christopher W. Stubbs
The feasibility of developing a network of telescopes to monitor the composition of the nighttime atmosphere using stellar spectrophotometry is explored. Spectral measurements of the extinction of starlight by the atmosphere would allow, for instance